Catalysis letters

Molecular structure effects in the asymmetric transfer hydrogenation of functionalized dihydroisoquinolines on (S, S)-[RuCl (η 6-p-cymene) TsDPEN]

…, V Matoušek, J Přech, S Bártová, M Kuzma, P Kačer

文献索引：Vaclavik, Jiri; Pechacek, Jan; Vilhanova, Beata; Sot, Petr; Januscak, Jakub; Matousek, Vaclav; Prech, Jan; Bartova, Simona; Kuzma, Marek; Kacer, Petr Catalysis Letters, 2013 , vol. 143, # 6 p. 555 - 562

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被引用次数: 8

摘要

Abstract The asymmetric transfer hydrogenation of five dihydroisoquinolines (DHIQs) was studied by NMR spectroscopy. The DHIQs differed by substitution with methoxy groups, which had a significant effect upon the reaction performance in terms of reaction rate and enantioselectivity. The differences are most probably related to the basicity of DHIQs. Graphical Abstract