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The Journal of Organic Chemistry

SRN1 reactions of some phosphorus nucleophiles with iodo-and bromobenzene

JE Swartz, JF Bunnett

文献索引:Swartz,J.E.; Bunnett,J.F. Journal of Organic Chemistry, 1979 , vol. 44, p. 4673 - 4677

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被引用次数: 20

摘要

Results Descriptive Studies. Our principal experiments are summarized in Table I. They concern four phosphanion nucleophiles not previously involved in SRNl reactions, namely, PhP (0Bu) O-, Ph, PO-,(EtO), PS-, and (Me2N) 2PO-. These can be regarded as analogues of the much-studied2?""(EtO), PO-. Whereas diethyl phosphite