Polyhedron

Study on the intramolecular transannular chalcogen–tin interactions in dithiastannecine compounds

…, N Andrade-López, T Pandiyan, R Moreno-Esparza…

文献索引：Martinez-Otero, Diego; Alvarado-Rodriguez, Jose G.; Cruz-Borbolla, Julian; Andrade-Lopez, Noemi; Pandiyan, Thangarasu; Moreno-Esparza, Rafael; Flores-Alamo, Marcos; Cantillo-Castillo, Jesus Polyhedron, 2012 , vol. 33, # 1 p. 367 - 377

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被引用次数: 8

摘要

Dithiastannecine compounds of the type [{D (C6H4CH2S) 2} SnR1R2] with different donor atoms D were prepared, where D= O and R1= R2= Ph (4a); R1= Ph, R2= Cl (5a); R1= n-Bu, R2= Cl (6a); D= S and R1= R2= Ph (4b); R1= Ph, R2= Cl (5b); R1= n-Bu, R2= Cl (6b). The molecular structures of the monochloro compounds 5a, 5b, 6a, and 6b were established by single-crystal X-ray diffraction and exhibit trigonal bipyramidal geometry at the tin atom ...