1, 5-Diborabicyclo [3.3. 3] undecane; thermolysis of the product from hydroboration of triallylborane with triethylamine–borane

RW Alder, Z Jin

文献索引：Alder, Roger W.; Jin, Zhao Journal of the Chemical Society - Perkin Transactions 1, 1996 , # 7 p. 657 - 660

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摘要

Attempts to reproduce the reported preparation of 1, 5-diborabicyclo [3.3. 3] undecane 1 through hydroboration of triallylborane with triethylamine–borane, followed by thermolysis, have led to 1, 5-dipropyl-1, 5-diborocane 2 and other products, but the presence of 1 could not be detected by GC–MS. Treatment of triallylborane with monobromoborane, methanolysis and subsequent thermolysis gave 1, 5-dimethoxy-1, 5-diborocane 3 which ...