Synthesis of dioxobis (tert-alkylimido) osmium (VIII) and oxotris (tert-alkylimido) osmium (VIII) complexes. Stereospecific vicinal diamination of olefins

AO Chong, K Oshima, KB Sharpless

文献索引：Chong,A.O. et al. Journal of the American Chemical Society, 1977 , vol. 99, p. 3420 - 3426

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被引用次数: 171

摘要

Synthesis of Dioxobis( tert- alkylimido)osmium( VIII) and ... Anthony 0. Chong, Koichiro Oshima, and K. Barry Sharpless* Contribution from the Department of Chemistry, Massachiisetrs Institute of Technology, Cambridge, Massachusetts 021 39. Receiced December 6, 1976 ... Abstract: The synthesis and properties of dioxobis(terr-butylimido)osmium(Vl II) (5) and oxotris(terr-butylimidojosmium- (VIII) (6) are described. Other tert-alkylimido derivatives ...