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Journal of Organometallic Chemistry

Elementorganische amin/imin-verbindungen: XV.[Bis (trimethylsilyl)] amino-nt-butylphospha (III) azen, ein reaktionsfähiges ylid des dreibindigen phosphors

OJ Scherer, N Kuhn

文献索引:Scherer,O.J.; Kuhn,N. Journal of Organometallic Chemistry, 1974 , vol. 82, p. C3 - C6

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被引用次数: 33

摘要

Abstract [Bis (trimethylsilyl)] amino-Nt-butylphospha (III) azene is made in a two step synthesis. It can be oxidized by sulfur and selenium to a stable monomeric metathio-and metaselenophosphoric acid derivative and it forms with methanol the bis (amino) phosphine derivative which can be oxidized by CCl 4 to the aminophospha (V) azene derivative.