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举例 :可输入Filippa Pettersson 或者 Cancer Res. 75(6) , 1102-12, (2015) 或者10.1002/anie.201600521

Photochemical synthesis. 65. Thione photochemistry. 22. Intramolecular cyclization of aralkyl thiones from S2

A Couture, K Ho, M Hoshino, P De Mayo…

文献索引：Couture,A. et al. Journal of the American Chemical Society, 1976 , vol. 98, p. 6218 - 6225

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被引用次数: 16

摘要

Abstract: Excitation of a series of aralkyl thiones into the S2 (T, T*) state leads to a formal insertion into the 6 position and the formation of cyclopentyl thiols. Excitation into the Si (n, T*) state does not lead to the same products and reaction is very slow. The former reaction may be quenched with biacetyl, but not with up to 2 M piperylene, nor can it be induced with a variety of triplet sensitizers. These and other observations make it probable that Sz is the ...

2,2,4-trimethyl-1-phenylcyclopentane-1-thiol结构式

2,2,4-trimethyl...

~%

(3,5,5-trimethylcyclopenten-1-yl)benzene结构式

(3,5,5-trimethy...

2,2,4-trimethyl-1-phenylpentane-1-thione结构式

2,2,4-trimethyl...

~%

(3,5,5-trimethylcyclopenten-1-yl)benzene结构式

(3,5,5-trimethy...

(R)-(-)-3-methyl-1-pentanol结构式

(R)-(-)-3-methy...

~%

(S)-1-溴-3-甲基戊烷结构式

(S)-1-溴-3-甲基戊烷

2,2-dimethyl-1-phenylpentan-1-one结构式

2,2-dimethyl-1-...

~%

2,2-dimethyl-1-phenylpentane-1-thione结构式

2,2-dimethyl-1-...

2,2,4-trimethyl-1-phenylpentan-1-one结构式

2,2,4-trimethyl...

~%

2,2,4-trimethyl-1-phenylpentane-1-thione结构式

2,2,4-trimethyl...

2,2-dimethyl-1-phenyltridecan-1-one结构式

2,2-dimethyl-1-...

~%

2,2-dimethyl-1-phenyltridecane-1-thione结构式

2,2-dimethyl-1-...

2,2,4-trimethyl-1-phenylpentan-1-one结构式

2,2,4-trimethyl...

~%

(3,5,5-trimethylcyclopenten-1-yl)benzene结构式

(3,5,5-trimethy...

2-Methyl-2-propyl-1-tetralon结构式

2-Methyl-2-prop...

~%

2-methyl-2-propyl-3,4-dihydronaphthalene-1-thione结构式

2-methyl-2-prop...

2-甲基-3,4-二氢-2H-1-萘酮结构式

2-甲基-3,4-二氢-2H-1-萘酮

~%

2-methyl-2-propyl-3,4-dihydronaphthalene-1-thione结构式

2-methyl-2-prop...

1-氧代-1,2,3,4-四氢萘-2-羧酸乙酯结构式

1-氧代-1,2,3,4-四氢...

~%

2-methyl-2-propyl-3,4-dihydronaphthalene-1-thione结构式

2-methyl-2-prop...

2-甲基-3,4-二氢-2H-1-萘酮结构式

2-甲基-3,4-二氢-2H-1-萘酮

~%

3a-methyl-2,3,4,5-tetrahydrocyclopenta[a]naphthalene结构式

3a-methyl-2,3,4...

1-氧代-1,2,3,4-四氢萘-2-羧酸乙酯结构式

1-氧代-1,2,3,4-四氢...

~%

3a-methyl-2,3,4,5-tetrahydrocyclopenta[a]naphthalene结构式

3a-methyl-2,3,4...

2-Methyl-2-propyl-1-tetralon结构式

2-Methyl-2-prop...

~%

3a-methyl-2,3,4,5-tetrahydrocyclopenta[a]naphthalene结构式

3a-methyl-2,3,4...

2-methyl-2-propyl-3,4-dihydronaphthalene-1-thione结构式

2-methyl-2-prop...

~%

3a-methyl-2,3,4,5-tetrahydrocyclopenta[a]naphthalene结构式

3a-methyl-2,3,4...

2,2,5,5-tetramethyl-1-phenylhexan-1-one结构式

2,2,5,5-tetrame...

~%

2,2,5,5-tetramethyl-1-phenylhexane-1-thione结构式

2,2,5,5-tetrame...

2,2-dimethyl-1-phenylbutan-1-one结构式

2,2-dimethyl-1-...

~%

2,2-dimethyl-1-phenylbutane-1-thione结构式

2,2-dimethyl-1-...

2,2-dimethyl-1,5-diphenylpentan-1-one结构式

2,2-dimethyl-1,...

~%

2,2-dimethyl-1,5-diphenylpentane-1-thione结构式

2,2-dimethyl-1,...

2,2-dimethyl-1-phenyltridecan-1-one结构式

2,2-dimethyl-1-...

~%

2,2-dimethyl-5-octyl-1-phenylcyclopentane-1-thiol结构式

2,2-dimethyl-5-...

2,2-dimethyl-1-phenyltridecane-1-thione结构式

2,2-dimethyl-1-...

~%

2,2-dimethyl-5-octyl-1-phenylcyclopentane-1-thiol结构式

2,2-dimethyl-5-...

2-butyl-2-methyl-3H-inden-1-one结构式

2-butyl-2-methy...

~%

2-butyl-2-methyl-3H-indene-1-thione结构式

2-butyl-2-methy...

2-甲基-1-茚酮结构式

2-甲基-1-茚酮

~%

2-butyl-2-methyl-3H-indene-1-thione结构式

2-butyl-2-methy...

2-甲基-1-茚酮结构式

2-甲基-1-茚酮

~%

1,3a-dimethyl-3,4-dihydro-2H-cyclopenta[a]indene结构式

1,3a-dimethyl-3...

2-butyl-2-methyl-3H-inden-1-one结构式

2-butyl-2-methy...

~%

1,3a-dimethyl-3,4-dihydro-2H-cyclopenta[a]indene结构式

1,3a-dimethyl-3...

2-butyl-2-methyl-3H-indene-1-thione结构式

2-butyl-2-methy...

~%

1,3a-dimethyl-3,4-dihydro-2H-cyclopenta[a]indene结构式

1,3a-dimethyl-3...

1-propanone, 1-(4-methoxyphenyl)-2-methyl-结构式

1-propanone, 1-...

~%

1-(4-methoxyphenyl)-2,2,5-trimethylcyclopentane-1-thiol结构式

1-(4-methoxyphe...

1-(4-methoxyphenyl)-2,2-dimethylhexan-1-one结构式

1-(4-methoxyphe...

~%

1-(4-methoxyphenyl)-2,2,5-trimethylcyclopentane-1-thiol结构式

1-(4-methoxyphe...

1-(4-methoxyphenyl)-2,2-dimethylhexane-1-thione结构式

1-(4-methoxyphe...

~%

1-(4-methoxyphenyl)-2,2,5-trimethylcyclopentane-1-thiol结构式

1-(4-methoxyphe...

2,2-dimethyl-1,5-diphenylpentan-1-one结构式

2,2-dimethyl-1,...

~%

2,2-dimethyl-1,5-diphenylcyclopentane-1-thiol结构式

2,2-dimethyl-1,...

2,2-dimethyl-1,5-diphenylpentane-1-thione结构式

2,2-dimethyl-1,...

~%

2,2-dimethyl-1,5-diphenylcyclopentane-1-thiol结构式

2,2-dimethyl-1,...

2,2-dimethyl-1-phenylhexane-1-thione结构式

2,2-dimethyl-1-...

~%

(2,5,5-trimethylcyclopenten-1-yl)benzene结构式

(2,5,5-trimethy...

2,2,4,5-tetramethyl-1-phenylcyclopentane-1-thiol结构式

2,2,4,5-tetrame...

~%

(2,3,5,5-tetramethylcyclopenten-1-yl)benzene结构式

(2,3,5,5-tetram...

S(-)-2-甲基-1-丁醇结构式

S(-)-2-甲基-1-丁醇

~%

(2,3,5,5-tetramethylcyclopenten-1-yl)benzene结构式

(2,3,5,5-tetram...

(S)-1-溴-2-甲基丁烷结构式

(S)-1-溴-2-甲基丁烷

~%

(2,3,5,5-tetramethylcyclopenten-1-yl)benzene结构式

(2,3,5,5-tetram...

(4S)-2,2,4-trimethyl-1-phenylhexan-1-one结构式

(4S)-2,2,4-trim...

~%

(2,3,5,5-tetramethylcyclopenten-1-yl)benzene结构式

(2,3,5,5-tetram...

(4S)-2,2,4-trimethyl-1-phenylhexane-1-thione结构式

(4S)-2,2,4-trim...

~%

(2,3,5,5-tetramethylcyclopenten-1-yl)benzene结构式

(2,3,5,5-tetram...

δ,δ-Dimethylhexanophenon结构式

δ,δ-Dimethylhex...

碘甲烷结构式

~%

2,2,5,5-tetramethyl-1-phenylhexan-1-one结构式

2,2,5,5-tetrame...

1-(4-methoxyphenyl)-2,2,5-trimethylcyclopentane-1-thiol结构式

1-(4-methoxyphe...

~%

1-methoxy-4-(2,5,5-trimethylcyclopenten-1-yl)benzene结构式

1-methoxy-4-(2,...

1-propanone, 1-(4-methoxyphenyl)-2-methyl-结构式

1-propanone, 1-...

~%

1-methoxy-4-(2,5,5-trimethylcyclopenten-1-yl)benzene结构式

1-methoxy-4-(2,...

1-(4-methoxyphenyl)-2,2-dimethylhexan-1-one结构式

1-(4-methoxyphe...

~%

1-methoxy-4-(2,5,5-trimethylcyclopenten-1-yl)benzene结构式

1-methoxy-4-(2,...

1-(4-methoxyphenyl)-2,2-dimethylhexane-1-thione结构式

1-(4-methoxyphe...

~%

1-methoxy-4-(2,5,5-trimethylcyclopenten-1-yl)benzene结构式

1-methoxy-4-(2,...

2,2-dimethyl-1-phenylpentan-1-one结构式

2,2-dimethyl-1-...

~%

2,2-dimethyl-1-phenylcyclopentane-1-thiol结构式

2,2-dimethyl-1-...

2,2-dimethyl-1-phenylpentane-1-thione结构式

2,2-dimethyl-1-...

~%

2,2-dimethyl-1-phenylcyclopentane-1-thiol结构式

2,2-dimethyl-1-...

2,2-dimethyl-5-octyl-1-phenylcyclopentane-1-thiol结构式

2,2-dimethyl-5-...

~%

(5,5-dimethyl-2-octylcyclopenten-1-yl)benzene结构式

(5,5-dimethyl-2...

2,2-dimethyl-1-phenyltridecane-1-thione结构式

2,2-dimethyl-1-...

~%

(5,5-dimethyl-2-octylcyclopenten-1-yl)benzene结构式

(5,5-dimethyl-2...

2,2-dimethyl-1-phenyltridecan-1-one结构式

2,2-dimethyl-1-...

~%

(5,5-dimethyl-2-octylcyclopenten-1-yl)benzene结构式

(5,5-dimethyl-2...

2,2-dimethyl-1,5-diphenylpentan-1-one结构式

2,2-dimethyl-1,...

~%

(3,3-dimethyl-2-phenylcyclopenten-1-yl)benzene结构式

(3,3-dimethyl-2...

2,2-dimethyl-1,5-diphenylpentane-1-thione结构式

2,2-dimethyl-1,...

~%

(3,3-dimethyl-2-phenylcyclopenten-1-yl)benzene结构式

(3,3-dimethyl-2...

S(-)-2-甲基-1-丁醇结构式

S(-)-2-甲基-1-丁醇

~%

(3-ethyl-5,5-dimethylcyclopenten-1-yl)benzene结构式

(3-ethyl-5,5-di...

(S)-1-溴-2-甲基丁烷结构式

(S)-1-溴-2-甲基丁烷

~%

(3-ethyl-5,5-dimethylcyclopenten-1-yl)benzene结构式

(3-ethyl-5,5-di...

(4S)-2,2,4-trimethyl-1-phenylhexan-1-one结构式

(4S)-2,2,4-trim...

~%

(3-ethyl-5,5-dimethylcyclopenten-1-yl)benzene结构式

(3-ethyl-5,5-di...

(4S)-2,2,4-trimethyl-1-phenylhexane-1-thione结构式

(4S)-2,2,4-trim...

~%

(3-ethyl-5,5-dimethylcyclopenten-1-yl)benzene结构式

(3-ethyl-5,5-di...

正溴丁烷结构式

1-propanone, 1-(4-methoxyphenyl)-2-methyl-结构式

1-propanone, 1-...

~%

1-(4-methoxyphenyl)-2,2-dimethylhexan-1-one结构式

1-(4-methoxyphe...

正溴丁烷结构式

1-[4-(dimethylamino)phenyl]-2-methylpropan-1-one结构式

1-[4-(dimethyla...

~%

1-[4-(dimethylamino)phenyl]-2,2-dimethylhexan-1-one结构式

1-[4-(dimethyla...

2-甲基-1-茚酮结构式

2-甲基-1-茚酮

~%

2-butyl-2-methyl-3H-inden-1-one结构式

2-butyl-2-methy...

S(-)-2-甲基-1-丁醇结构式

S(-)-2-甲基-1-丁醇

~%

2,2,4,5-tetramethyl-1-phenylcyclopentane-1-thiol结构式

2,2,4,5-tetrame...

(S)-1-溴-2-甲基丁烷结构式

(S)-1-溴-2-甲基丁烷

~%

2,2,4,5-tetramethyl-1-phenylcyclopentane-1-thiol结构式

2,2,4,5-tetrame...

(4S)-2,2,4-trimethyl-1-phenylhexan-1-one结构式

(4S)-2,2,4-trim...

~%

2,2,4,5-tetramethyl-1-phenylcyclopentane-1-thiol结构式

2,2,4,5-tetrame...

(4S)-2,2,4-trimethyl-1-phenylhexane-1-thione结构式

(4S)-2,2,4-trim...

~%

2,2,4,5-tetramethyl-1-phenylcyclopentane-1-thiol结构式

2,2,4,5-tetrame...

1-(4-methoxyphenyl)-2,2-dimethylhexan-1-one结构式

1-(4-methoxyphe...

~%

1-(4-methoxyphenyl)-2,2-dimethylhexane-1-thione结构式

1-(4-methoxyphe...

1-propanone, 1-(4-methoxyphenyl)-2-methyl-结构式

1-propanone, 1-...

~%

1-(4-methoxyphenyl)-2,2-dimethylhexane-1-thione结构式

1-(4-methoxyphe...