Chemical Communications

Ethylene trimerization with a half-sandwich titanium complex bearing a pendant thienyl group

J Huang, T Wu, Y Qian

文献索引：Huang, Jiling; Wu, Tianzhi; Qian, Yanlong Chemical Communications, 2003 , # 22 p. 2816 - 2817

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被引用次数: 39

摘要

A half-sandwich titanium complex with a pendant thienyl group, activated by methylalumoxane (MAO), can trimerize ethylene to 1-hexene with considerable activity and high selectivity; the coodination of the sulfur atom to the titanium center is proposed to be responsible for the selective trimerization of ethylene.