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Conformation of dimethylaminoethanol, its methyl ether and of the corresponding trimethylammonium iodides. NMR and vibrational spectra

J Štokr, B Schneider, D Doskočilová…

文献索引:Stokr, Jan; Schneider, Bohdan; Doskocilova, Danica; Sevcik, Stanislav; Pradny, Martin Collection of Czechoslovak Chemical Communications, 1987 , vol. 52, # 5 p. 1256 - 1271

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被引用次数: 4

摘要

Abstract By analysis of fully coupled 13 C NMR spectra and of 1 H NMR spectra of dimethylaminoethanol, its methyl ether, and of the corresponding trimethylammonium iodides, populations of isomers generated by rotation about the bonds N-CH 2, CH 2-CH 2, and CH 2-O in these compounds in solution were determined. By analysis of Raman and infrared spectra of these compounds in the solid and liquid states it was found that in the ...