Bespoke Photoreductants: Tungsten Arylisocyanides

W Sattler, LM Henling, JR Winkler…

文献索引：Sattler, Wesley; Ener, Maraia E.; Blakemore, James D.; Rachford, Aaron A.; Labeaume, Paul J.; Thackeray, James W.; Cameron, James F.; Winkler, Jay R.; Gray, Harry B. Journal of the American Chemical Society, 2013 , vol. 135, # 29 p. 10614 - 10617

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被引用次数: 12

摘要

Modular syntheses of oligoarylisocyanide ligands that are derivatives of 2, 6- diisopropylphenyl isocyanide (CNdipp) have been developed; tungsten complexes incorporating these oligoarylisocyanide ligands exhibit intense metal-to-ligand charge- transfer visible absorptions that are red-shifted and more intense than those of the parent W (CNdipp) 6 complex. Additionally, these W (CNAr) 6 complexes have enhanced excited- ...