Synthesis of selected naturally occurring glucosides of volatile compounds. Their chromatographic and spectroscopic properties

J Mastelić, I Jerković, M Vinković, Z Džolić…

文献索引：Mastelic, Josip; Jerkovic, Igor; Vinkovic, Marijana; Dzolic, Zoran; Vikic-Topic, Drazen Croatica Chemica Acta, 2004 , vol. 77, # 3 p. 491 - 500

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被引用次数: 40

摘要

Sažetak Naturally occurring glucosides of benzyl alcohol,(±)-menthol,(+)-borneol, thymol, carvacrol and eugenol were synthesized by the Koenigs-Knorr-Zemplén method (yields 19.5– 52.2%). Their β-D-glucopyranosidic structures were determined by one-and two- dimensional homoand heteronuclear 1 H and 13 C NMR spectroscopy. The β-configuration was additionally confirmed by the hydrolysis with β-glucosidase. Tetraacetyl-β-D- ...