The Enantiospecific, Stereospecific Total Synthesis of the Ring-A Oxygenated Sarpagine Indole Alkaloids (+)-Majvinine,(+)-10-Methoxyaffinisine, and (+)-N a- …
…, T Wang, J Flippen-Anderson, JM Cook
文献索引：Zhao, Shuo; Liao, Xuebin; Wang, Tao; Flippen-Anderson, Judith; Cook, James M. Journal of Organic Chemistry, 2003 , vol. 68, # 16 p. 6279 - 6295
The first stereospecific, enantiospecific total synthesis of the ring-A oxygenated sarpagine indole alkaloids (+)-N a-methylsarpagine (8),(+)-majvinine (14), and (+)-10- methoxyaffinisine (49), as well as the first total synthesis of the Alstonia bisindole alkaloid macralstonidine (9), has been accomplished. This approach employed the Schöllkopf chiral auxiliary for the stereospecific construction of the desired d-(+)-tryptophan unit required for ...
