Journal of organometallic chemistry

15 N and 13 C NRM studies on cyclopalladated complexes Synthetic palladium cyanide chemistry leading to organic nitriles

S Affolter, PS Pregosin

文献索引：Affolter, Samuel; Pregosin, Paul S. Journal of Organometallic Chemistry, 1990 , vol. 398, # 1/2 p. 197 - 204

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被引用次数: 5

摘要

Abstract 15 N NMR spectroscopy has been used to determine whether the 15 NO group is coordinated in the cyclopalladated nitrosoamine complex [Pd (μ-OAc)(O NN-(CH 3) C 6 H 4)] 2, PdCl {O NN (CH 3) C 6 H 4}{P (OMe) 3} and K 2 [Pd (CN) 3 (O NN-(CH 3) C 6 H 4)], 11, as well as in several platinum (II) analogs. 13 C NMR studies on 11, the cyclopalladated N, N-dimethylbenzylamine analog K 2 [Pd (CN) 3 (Me 2 NCH 2 C 6-H 4)], 12, and the ...