Structural properties of the metallointercalator cationic complex (2, 2′: 6′, 2 ″-terpyridine) methylplatinum (II) ion
R Romeo, LM Scolaro, MR Plutino, A Albinati
文献索引：Romeo, Raffaello; Scolaro, Luigi Monsu; Plutino, Maria Rosaria; Albinati, Alberto Journal of Organometallic Chemistry, 2000 , vol. 593-594, p. 403 - 408
The complex [Pt (tpy)(Me)]+(BPh4)−(tpy= 2, 2′: 6′, 2′′-terpyridine) crystallizes in the triclinic space group P1̄ with a= 13.463 (2) Å, b= 13.618 (3) Å, c= 20.151 (4) Å, α= 73.59 (2), β= 74.56 (3), γ= 65.82 (2)° and Z= 4. The final conventional R factor is 0.035. In the unit cell a couple of weakly interacting dimers are formed by stack of two [Pt (tpy)(Me)]+ cations in a head-to-tail fashion with intermolecular Pt⋯ Pt distances of 4.437 (1) and 4.931 (1) Å, ...
