Journal of fluorine chemistry

Spin trapping of fluoroalkyl radicals

L Gille, R Stoesser

文献索引：Gille, Lars; Stoesser, Reinhard Journal of Fluorine Chemistry, 1994 , vol. 69, # 2 p. 191 - 194

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被引用次数: 9

摘要

Abstract The formation of fluoroalkyl radicals in liquid chlorofluorocarbons (CF 2 Cl-CFCl 2, CFCl 3, CFCl 2-CH3, CHF 2-CF 2-CF 2 Cl, CF 3-CFH-CF 3 and CCl 4) has been investigated by means of the spin trapping technique and ESR spectroscopy. It is shown that the primary fluoroalkyl radicals which were generated in these compounds by ionising radiation are preferably formed by bond cleavage at carbon atoms attached to one ...