Hofmann rearrangement of carboxamides mediated by hypervalent iodine species generated in situ from iodobenzene and oxone: Reaction scope and limitations
... Volume: Page: ... a All reactions of amides 8a−f (1 mmol) were performed at room temperature in the presence of PhI (1 equiv) and Oxone (2 equiv) in CH 3 CN−H 2 O (1:1, v/v) (6 mL). b ... chem. and is now firmly established as a versatile synthetic reagent. ...
