(C 5 Me 5) SiMe 3 as a mild and effective reagent for transfer of the C 5 Me 5 ring: an improved route to monopentamethylcyclopentadienyl trihalides of the group 4 …

…, M Mena, F Palacios, P Royo, R Serrano

文献索引：Llinas, Gerardo Hidalgo; Mena, Miguel; Palacios, Federico; Royo, Pascual; Serrano, Ricardo Journal of Organometallic Chemistry, 1988 , vol. 340, p. 37 - 40

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被引用次数: 28

摘要

Abstract The reaction between (C 5 Me 5) SiMe 3 and group 4 element tetrahalides MX 4 (M Ti, X Cl, Br, I; M Zr and Hf, X Cl) gives the corresponding (η 5-C 5 Me 5) MX 3 derivatives in nearly quantitative yields in a one-step procedure without the need for further purification.