Synthesis and metallation of ferrocenylimines derived from ligating diaminoheteroarenes

…, W áEdward Lindsell, AB Padias, PN Preston

文献索引：Asselin, Catherine M.; Fraser, Greig C.; Hall Jr.; Lindsell, W. Edward; Padias, Anne B.; Preston, Peter N. Journal of the Chemical Society - Dalton Transactions, 1997 , # 20 p. 3765 - 3771

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被引用次数: 11

摘要

A regioisomeric mixture of 1, 1′-didodecylferrocenedicarbaldehydes 3 was prepared from the reaction of a regioisomeric mixture of 1, 1′-didodecyldilithioferrocenes and dimethylformamide. Three ligating heteroaromatics were synthesized each containing two amino substituents: 5, 5′-diamino-2, 2′-bipyridine and 5, 5 ″-diamino-2, 2′∶ 6′, 2 ″- terpyridine were prepared from appropriate dinitro compounds by reduction with ...