The 4, 4'-(1, 2-Ethanediyl) bisbenzyl Biradical: Its Generation, Detection, and (Photo) chemical Behavior in Solution

…, E Font-Sanchis, J Pérez-Prieto…

文献索引：Miranda; Font-Sanchis; Perez-Prieto; Scaiano Journal of Organic Chemistry, 2001 , vol. 66, # 8 p. 2717 - 2721

被引用次数: 12

摘要

The 4, 4'-(1, 2-ethanediyl) bisbenzyl biradical (2) is clearly and efficiently generated by photolysis of [3.2] paracyclophane-2-one (8) in cyclohexane solution. This intermediate is also formed via two-photon processes from [2.2] paracyclophane (3) and 1, 2-bis (4- chloromethylphenyl) ethane (4). The products arising thermally from biradical 2 are [2.2] paracyclophane and [2.2. 2.2] paracyclophane (11)(under high-intensity conditions). ...

1633-22-3

对二甲苯二聚体

~90%

Macro Rings. XXXIII. A 1, 6 to 1, 6 Cycloaddition Reaction, ...

[Cram,D.J. et al. Journal of the American Chemical Society, 1966 , vol. 88, # 3 p. 515 - 525]

Alternative General Synthetic Routes to [2.2] Cyclophanes an...

[Isaji, Hajime; Yasutake, Mikio; Takemura, Hiroyuki; Sako, Katsuya; Tatemitsu, Hitoshi; Inazu, Takahiko; Shinmyozu, Teruo European Journal of Organic Chemistry, 2001 , # 13 p. 2487 - 2499]

A new synthetic method of [2.2] cyclophanes

[Takemura, Hiroyuki; Shinmyozu, Teruo; Inazu, Takahiko Tetrahedron Letters, 1988 , vol. 29, # 9 p. 1031 - 1032]

[2.2. 2] paracyclophane, a novel type of metal cation comple...

[Pierre,J.L.; Baret,P.; Chautemps,P. Journal of the American Chemical Society, 1981 , vol. 103, p. 2986]

A new synthetic method of [2.2] cyclophanes

[Takemura, Hiroyuki; Shinmyozu, Teruo; Inazu, Takahiko Tetrahedron Letters, 1988 , vol. 29, # 9 p. 1031 - 1032]