Regio-and Stereochemistry on the Electrophilic Trapping of Allylic Samariums Generated by Reductive Cleavage of Allylic Ethers with (C5Me5) 2Sm (thf) n

…, T Nishiyama, T Kamata, M Yokoyama…

文献索引：Takaki, Ken; Kusudo, Takeshi; Uebori, Shinya; Nishiyama, Tetsushi; Kamata, Tohru; Yokoyama, Masaki; Takehira, Katsuomi; Makioka, Yoshikazu; Fujiwara, Yuzo Journal of Organic Chemistry, 1998 , vol. 63, # 13 p. 4299 - 4304

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被引用次数: 17

摘要

The CO bond of allylic benzyl ethers was selectively cleaved with Cp* 2Sm (thf) n to give allylic samarium complexes in good yields. Facility of their bond fission has been found to be comparable to that of the corresponding propargylic ethers intermolecularly, but lower intramolecularly. Regio-and stereochemistry on the electrophilic trapping of the allylic complexes thus generated remarkably depended on the nature of the electrophiles. They ...