Reversal of Diastereoselectivities in Intra-and Intermolecular Reactions of 2-Adamantanylidenes Primarily Caused by Electron-Donating and Electron-Withdrawing …
... Volume: Page ... Organic Letters. ... Since computations for the trimethylsilyl group were most promising, 4-azi-1-(trimethylsilyl)adamantane (10) was synthesized (Scheme 3). The required 5-(trimethylsilyl)adamantan-2-one (8) was prepared according to the literature ...
