Configuration and Conformation of So-called Bis (alkylidenearylamines)

M Funabashi, M Iwakawa, J Yoshimura

文献索引：Funabashi et al. Bulletin of the Chemical Society of Japan, 1969 , vol. 42, p. 2885

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被引用次数: 19

摘要

The proposed structures of the dimeric products obtained from aliphatic aldehydes and arylamines were reexamined by IR and NMR spectra. The 1, 2, 3, 4-tetrahydroquinoline structure was ascertained in the case of acetaldehyde or propionaldehyde, and aldolic structure was confirmed in the case of n-butyraldehyde. It was observed that the latter readily isomerizes to the former type in the presence of acetic acid. Conformational analysis of a ...