Organic letters

Enantioselective Approach to (−)-Hamigeran B and (−)-4-Bromohamigeran B via Catalytic Asymmetric Hydrogenation of Racemic Ketone To Assemble the Chiral …

H Lin, LJ Xiao, MJ Zhou, HM Yu, JH Xie, QL Zhou

文献索引：Liu, Chong; Xie, Jian-Hua; Li, Ya-Li; Chen, Ji-Qiang; Zhou, Qi-Lin Angewandte Chemie - International Edition, 2013 , vol. 52, # 2 p. 593 - 596 Angew. Chem., 2013 , vol. 125, # 2 p. 621 - 624,4

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被引用次数: 2

摘要

A new strategy featuring an iridium-catalyzed asymmetric hydrogenation of a racemic ketone via dynamic kinetic resolution to generate a cyclopentanol with three contiguous stereocenters and a SmI2-promoted pinacol coupling to install the six-membered ring with