Some reactions and properties of molecular diatomic carbon C2. An experimental and theoretical treatment
…, LM Jackman, S Ahmed, ML McKee…
文献索引：Skell, Philip S.; Jackman, Lloyd M.; Ahmed, Sheikh; McKee, Michael L.; Shevlin, Philip B. Journal of the American Chemical Society, 1989 , vol. 111, # 12 p. 4422 - 4429
Abstract: Diatomic carbon, C2, reacts with propylene and (E)-and (Z)-2-butene in the condensed phase at 77 K. Products can be rationalized by a mechanism involving initial addition of C2 to the alkene to generate a 1, 4-diradical. This diradical may then either abstract hydrogens or add another alkene molecule to give a 1, 6-diradical which disproportionates to an enyne. Thus, reaction of C2 with propene gives 1-pentyne, 3- ...
