Organometallics

Syntheses of the ruthenium (VI) alkyl complexes [Ru (N) R4-xClx]-(R= Me, CH2SiMe3) and the x-ray crystal structure of [NBu4][Ru (N) Me4]

PA Shapley, HS Kim, SR Wilson

文献索引：Shapley, Patricia A.; Kim, Hoon sik; Wilson, Scott R. Organometallics, 1988 , vol. 7, p. 928 - 933

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被引用次数: 48

摘要

A, b= 18.368 (4) A, c= 15.193 (5) A; V= 2519 (1) A3; 2= 4; fi= 105.31 (2) O; pdd= 1.101 g/cm3, monoclinic space group E1/n. Mixed alkyl-chloro complexes,[Ru (N) R4, C1,]-(R= CH2SiMe3, x= 1-2; R= Me, x= 1-3), result from the reaction of HCl (g) with the alkyl complexes. The gold (1) chloro complex Au (PPh3) C1 reacts in a manner analogous to HC1 and converts [Ru (N) Me4]-to [Ru (N) C1Me3]-with formation of Au (PPh,) Me. In ...