The oxidation of alcohols in N-oxyl-immobilized silica gel/aqueous NaOCl disperse systems. A prominent access to a column-flow system

H Tanaka, J Chou, M Mine, M Kuroboshi

文献索引：Tanaka, Hideo; Chou, Jingyu; Mine, Machiko; Kuroboshi, Manabu Bulletin of the Chemical Society of Japan, 2004 , vol. 77, # 9 p. 1745 - 1755

全文：HTML全文

被引用次数: 24

摘要

The oxidation of alcohols was performed successfully in a disperse system with N-oxyl- adsorbed or immobilized silica gel as a disperse phase and aqueous NaOCl as a disperse medium. In the disperse system, the oxidation of sec-alcohols afforded the corresponding ketones, while prim-alcohols were oxidized to aldehydes and/or carboxylic acids depending on their structures and reaction conditions. The N-oxyl-immobilized silica gel was ...