Capture of nerve agents and mustard gas analogues by hydrophobic robust MOF-5 type metal–organic frameworks

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文献索引：Montoro, Carmen; Linares, Fatima; Quartapelle Procopio, Elsa; Senkovska, Irena; Kaskel, Stefan; Galli, Simona; Masciocchi, Norberto; Barea, Elisa; Navarro, Jorge A. R. Journal of the American Chemical Society, 2011 , vol. 133, # 31 p. 11888 - 11891

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被引用次数: 113

摘要

In this communication, a series of observations and data analyses coherently confirms the suitability of the novel metal–organic framework (MOF)[Zn4 (μ4-O)(μ4-4-carboxy-3, 5- dimethyl-4-carboxy-pyrazolato) 3](1) in the capture of harmful volatile organic compounds (VOCs). It is worthy of attention that 1, whose crystal structure resembles that of MOF-5, exhibits remarkable thermal, mechanical, and chemical stability, as required if practical ...