Vectorial Electron Transfer in Donor–Photosensitizer–Acceptor Triads Based on Novel Bis??tridentate Ruthenium Polypyridyl Complexes

…, D Streich, A Rolandini Jensen, M Jäger…

文献索引：Kumar, Rohan J.; Karlsson, Susanne; Streich, Daniel; Jensen, Alice Rolandini; Jaeger, Michael; Becker, Hans-Christian; Bergquist, Jonas; Johansson, Olof; Hammarstroem, Leif Chemistry - A European Journal, 2010 , vol. 16, # 9 p. 2830 - 2842

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被引用次数: 39

摘要

Abstract The first examples of rodlike donor–photosensitizer–acceptor arrays based on bis- 2, 6-di (quinolin-8-yl) pyridine Ru II complexes 1 a and 3 a for photoinduced electron transfer have been synthesized and investigated. The complexes are synthesized in a convergent manner and are isolated as linear, single isomers. Time-resolved absorption spectroscopy reveals long-lived, photoinduced charge-separated states (τ CSS (1 a)= 140 ns, τ CSS (3 ...