Comparative reactivity of isoelectronic nitrido, methylimido, and oxo complexes of osmium (VI)

RW Marshman, PA Shapley

文献索引：Marshman, Robert W.; Shapley, Patricia A. Journal of the American Chemical Society, 1990 , vol. 112, # 23 p. 8369 - 8378

全文：HTML全文

被引用次数: 39

摘要

Abstract: The structures, physical properties, and reaction chemistry of isoelectronic alkyl complexes of osmium (V1) are compared. The three, five-coordinate alkyl complexes [NBun4][Os (N)(CH2SiMe3),], Os (NMe)(CH2SiMe3),, and Os (O)(CH, SiMe,), have been characterized by single-crystal X-ray diffraction, NMR, IR, UV-visible spectroscopy, and by electrochemical techniques. All have a square-pyramidal structure in the solid state, with ...