Reactions of monogermylarsine and monogermylphosphine with water and hydrogen sulphide

JE Drake, C Riddle

文献索引：Drake; Riddle Journal of the Chemical Society [Section] A: Inorganic, Physical, Theoretical, 1968 , p. 2709

全文：HTML全文

被引用次数: 4

摘要

Water assists the condensation of monogermylarsine and monogermylphosphine to form the trigermyl species by way of digermylarsine and digermylphosphine both of which are isolated. On the other hand, hydrogen sulphide reacts with the monogermyl species to give digermyl sulphide by way of germanethiol. The reactions have been followed by 1H nmr spectroscopy, and the spectra of several of the compounds are discussed. Methods of ...