Tetrahedron Letters

Enantioselective hydrosilylation of ketimines with trichlorosilane promoted by chiral N-picolinoylaminoalcohols

H Zheng, J Deng, W Lin, X Zhang

文献索引：Zheng, Hongjie; Deng, Jingen; Lin, Wenqing; Zhang, Xiaomei Tetrahedron Letters, 2007 , vol. 48, # 45 p. 7934 - 7937

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被引用次数: 67

摘要

Enantioselective hydrosilylation of N-aryl and N-benzyl ketimines with trichlorosilane catalyzed by readily accessible chiral N-picolinoylaminoalcohols proceeded smoothly furnishing chiral secondary amines in good yields (up to 93%) and moderate to excellent enantioselectivities (up to 95% ee).