Chemical Physics Letters

Kinetics of CN radical reactions with NOx between 297 and 740 K

NS Wang, DL Yang, MC Lin

文献索引：Wang, Niann S.; Yang, David L.; Lin, M. C. Chemical Physics Letters, 1989 , vol. 163, p. 480 - 484

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被引用次数: 32

摘要

Abstract The kinetics of the reaction of CN radicals with NO and NO 2 have been studied with the two-laser pump-probe technique at temperatures between 297 and 740 K over a broad range of pressure. The CN+ NO reaction was found to be strongly pressure dependent and the rate constant measured at 100 Torr of Ar has a negative temperature coefficient of 10.4 kJ/mol. These results suggest that the reaction occurs mainly be ...