Inorganic Chemistry

Some chemistry of difluoraminocarbonyl fluoride, NF2CFO. The preparation of perfluorourea,(NF2) 2CO, and difluoraminocarbonyl chloride, NF2C (O) Cl. New …

GW Fraser, JM Shreeve

文献索引：Fraser, G. W.; Shreeve, J. M. Inorganic Chemistry, 1967 , vol. 6, p. 1711 - 1715

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摘要

Reactions of NFzCFO with CFIOF or with AlzCls and HCl yield NFzOCF3 or NFzC (0) C1, respectively. The reactions of NFzCFO with KF and CsF to give KOCFZNFZ, KOCNzFs, KOCNaFe, CSOCFZNFZ, CSOCNZF~, and CsOCN3F6 are discussed. Decomposition of KOCFzNFz with CIZ yields NFZCl and pyrolysis of KOCNZF~ at 95" yields (NFz) zCO. Spectra and properties of (NF2) zCO and KF2 (0) Cl arc given.