The Journal of Organic Chemistry

General approach to the synthesis of bridgehead-bridgehead disubstituted bicyclo [n. 1.1] alkanes

PM Warner, BL Chen, E Wada

文献索引：Warner, Philip M.; Chen, Bing-Lin; Wada, Eiji Journal of Organic Chemistry, 1981 , vol. 46, # 23 p. 4795 - 4797

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被引用次数: 7

摘要

Our interest in bridgehead olefins3 and paddlanes4 has necessitated the synthesis of some bicyclo [nll] alkanes in which both bridgeheads are substituted with functionalized groups. In particular, we have been pursuing the group of diesters 1, of which la5 and lb6 are known. This report relates a simple, general approach (eq l), so far successful for lb-ld. I6