The Journal of Organic Chemistry

Silyl phosphites. 16. Mechanism of the Perkow reaction and the Kukhtin-Ramirez reaction. Elucidation by means of a new type of phosphoryl rearrangements utilizing …

M Sekine, M Nakajima, T Hata

文献索引：Sekine, Mitsuo; Nakajima, Masashi; Hata, Tsujiaki Journal of Organic Chemistry, 1981 , vol. 46, # 20 p. 4030 - 4034

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被引用次数: 20

摘要

Reactions of a-lithiated diethyl a-[(trimethylsilyl) oxy] benzylphosphonate (4) with benzoyl chloride and chloroiodomethane afforded benzoylated and chloromethylated products (1 and 2) corresponding to the 1: l carbonyl adducts of diethyl trimethylsilyl phosphite with benzil and phenacyl chloride which were not obtained by the reactions between the phosphite and benzil or phenacyl chloride. Pyrolysis of 1 and 2 afforded 1, 3, 2- ...