Tetrahedron: Asymmetry

Synthesis of new chiral thiazoline-containing ligands

I Abrunhosa, M Gulea, J Levillain, S Masson

文献索引：Abrunhosa, Isabelle; Gulea, Mihaela; Levillain, Jocelyne; Masson, Serge Tetrahedron Asymmetry, 2001 , vol. 12, # 20 p. 2851 - 2859

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被引用次数: 58

摘要

New chiral ligands, including bi-and tridentate thiazoline derivatives, analogues of known oxazolines, have been synthesized by a general and convenient procedure, starting from dithioesters and commercial enantiopure 2-aminoalcohols. A preliminary test shows the ability of such ligands to act as asymmetric catalysts in Pd-catalyzed allylic substitution reaction.