Reactions of enolic biotin models

H Kondo, K Miura, E Seki, J Sunamoto

文献索引：Kondo, Hiroki; Miura, Katsuhito; Seki, Eiji; Sunamoto, Junzo Bulletin of the Chemical Society of Japan, 1985 , vol. 58, # 10 p. 2801 - 2804

全文：HTML全文

被引用次数: 4

摘要

In order to delineate the mechanism of biotin-dependent carboxylation reactions, the following model experiments have been carried out. In reactions of carbonate derivatives such as methyl chloroformate with 2-ethoxy-2-imidazoline (1), a putative enolic biotin model, or 2-imidazolidinone (2), the former showed a much higher reactivity to provide the methoxycarbonylated 1 (3). Reactions of 3 with benzenethiolate, cyclohexylamine and ...