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1, 3, 4, 6-Tetra-O-acetyl-2-azido-2-deoxy-β-D-glucopyranose from D-glucosamine

F Dasgupta, PJ Garegg

文献索引:Dasgupta, Falguni; Garegg, Per J. Journal of the Chemical Society, Chemical Communications, 1989 ,  # 21  p. 1640 - 1641

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被引用次数: 7

摘要

A new method which is quick and efficient has been developed for the preparation of the above azido compound (1) from 1,3,4,6-tetra- 0-acetyl-2-N- benzyl-2-deoxy-PDg lucopyra nose. ... 2-Azido-2-deoxy-~-glucopyranose derivatives have been extensively used during the synthesis of complex oligosac- charides containing cx-linked N-acetyl-D-glucosamine moie- ties.' These have been prepared by azido-nitration,zJ or chloroazidation4 of D-glucal derivatives, by ...