Pheromone, 76. Synthese der Enantiomeren von 10??Methyldodecylacetat und 12??Methyltetradecylacetat, chiralen Pheromonkomponenten von Adoxophyes??Arten ( …

HJ Bestmann, RTS Frighetto, N Frighetto…

文献索引：Bestmann, Hans Juergen; Frighetto, Rosa T. S.; Frighetto, Nelson; Vostrowsky, Otto Liebigs Annalen der Chemie, 1990 ,  # 8  p. 829 - 831

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被引用次数: 3

摘要

From enantiomeric (R)-(-)-and (S)-(+)-2-methylbutyl bro-active methyl-branched olefinic THP ethers 12 and 13, mide (3), available by resolution of (R)-(-)-phenylglycinol am-hydrolysis, catalytic hydrogenation, and acetylation gave rise ides of rac-2-methylbutanoic acid, and from enantiomeric to the formation of the chiral title compounds (R)-(-)-and 6-methyloctyl bromide (7) the corresponding phosphonium (S)-(+)-10-methyldodecyl acetate (1) and (R) ...