A flow tube study of ion-molecule reactions of acetylene

…, CG Freeman, MJ McEwan, VG Anicich…

文献索引：Knight, J. S.; Freeman, C. G.; McEwan, M. J.; Anicich, V. G.; Huntress, W. T. Journal of Physical Chemistry, 1987 , vol. 91, # 14 p. 3898 - 3902

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被引用次数: 31

摘要

The reactivities of C2Hy+, C4Hy+, and C6Hy+(0 I y I 7) ions with acetylene have been investigated with a selected ion flow tube operating at room temperature. Rate coefficients and products for each reactant ion have been identified. The predominant mechanism observed was association thereby providing a pathway for the efficient conversion of C2Hy+ cations into C6-and C8-based cyclic hydrocarbons. Significant differences were noted in ...