In situ generation and synthetic applications of anhydrous hydrogen fluoride in a solid-liquid biphasic system

G Rothenberg, M Royz, O Arrad…

文献索引：Rothenberg, Gadi; Royz, Michael; Arrad, Onn; Sasson, Yoel Journal of the Chemical Society - Perkin Transactions 1, 1999 , # 11 p. 1491 - 1494

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被引用次数: 7

摘要

The generation of anhydrous HF by reaction of solid CaF with HSO in the presence of an organic phase containing the substrate is proposed as a simple and safe alternative to other fluorination methods. Using this method, the addition of HF to olefins to produce fluoroalkanes, the substitution of hydroxy and halide