Enantioselective synthesis of benzylic stereocentres via Claisen rearrangement of enantiomerically pure allylic alcohols: preparation of (R)-and (S)-3-methyl-2- …
... Tetrahedron: Asymmetry. Volume 14, Issue 16, 15 August 2003, Pages 2401–2406. ... alternative, the isopropyl moiety has been introduced by enantioselective alkylation of the benzylic carbon atom (C 11 , D 12 ), or by enantioselective addition to double bonds (E 13 , F 14., , , and ...
