A simple synthesis and some synthetic applications of substituted phosphide and phosphinite anions

…, NA Bondarenko, IG Malakhova, MI Kabachnik

文献索引：Tsvetkov, E. N.; Bondarenko, N. A.; Malakhova, I. G.; Kabachnik, M. I. Synthesis, 1986 , # 3 p. 198 - 208

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被引用次数: 45

摘要

Based on data for the acidity relationship of phosphines and phosphinous acids and water: 11 dimet. hyl sulfoxide and water, 21 simple method is reported for the generation of phosphide and phosphinite anions by the action ofeon» ccntratcd aqueous alkali on primary and secondary phosphines as well as phosphinous acids in dimethyl sulfoxidc or other dipolar aprotic solvents. Alkylalion of the anion yields secondary and tertiary phosphines, ...