Dalton Transactions

Preparation and characterization of mixed-ligand cobalt (III) complexes containing (3-aminopropyl) dimethylphosphine (pdmp). Conformation of the six-membered …

…, K Fujiiwara, HD Takagi, K Kashiwabara

文献索引：Suzuki, Takayoshi; Fujiiwara, Katsuhiro; Takagi, Hideo D.; Kashiwabara, Kazuo Dalton Transactions, 2007 , # 3 p. 308 - 319

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被引用次数: 2

摘要

Several new cobalt (III) complexes containing (3-aminopropyl) dimethylphosphine (pdmp) have been prepared, and their molecular structures have been determined. A dichloro complex of trans (Cl, Cl)-cis (P, P)-[CoCl2 (pdmp) 2] PF6 (1) was prepared from trans-[CoCl2 (py) 4] Cl· 6H2O and pdmp. X-Ray crystallography confirmed the (C2)-chair2 conformation of two six-membered pdmp chelate rings in 1, while the analogous 1, 3-bis ( ...