A bis (η 5-cyclopentadienyl) cobalt complex of a bis-dithiolene: a chemical analogue of the metal centres of the DMSO reductase family of molybdenum and tungsten …
FA Alphonse, R Karim, C Cano-Soumillac, M Hebray…
文献索引：Alphonse, France-Aimee; Karim, Rehana; Cano-Soumillac, Celine; Hebray, Marielle; Collison, David; Garner, C. David; Joule, John A. Tetrahedron, 2005 , vol. 61, # 46 p. 11010 - 11019
The synthesis is described of a bis-ene-1, 2-dithiolate pro-ligand, designed to model the stereochemical situation in the cofactor of the tungsten enzyme ferredoxin aldehyde oxidoreductase from Pyrococcus furiosus. Each masked ene-1, 2-dithiolate unit is mounted on a pyrano [2, 3-b] tetrahydroquinoxaline tricycle, comparable to the pyrano [2, 3-g] tetrahydropteridines found in all molybdoenzymes and tungsten analogues. Hydrolytic ...
