Chemistry Letters

Photosensitive 1: 1 Adduct between Bis (1, 2-diphenyl-1, 2-ethylenedithiolato) nickel (0) and Quadricyclane

…, M Kohara, T Kitayama, Y Asano, A Sugimori

文献索引：Kajitani, Masatsugu; Kohara, Midori; Kitayama, Tomoko; Asano, Yoshihiko; Sugimori, Akira Chemistry Letters, 1986 , p. 2109 - 2112

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被引用次数: 10

摘要

Bis (1, 2-diphenyl-1, 2-ethylenedithiolato) nickel (0)(1a) reacts with quadricyclane (Q) to give a 1: 1 adduct which has the same structure as that of the adduct between 1a and norbornadiene (NBD). Q reacts with 1a much faster than NBD. The adduct is thermally stable but photosensitive to dissociate into 1a and NBD.