Zur hydrolyse von monoorganylzinn-trihalogeniden III. Isolierung und röntgenstrukturanalyse von verbindungen mit dem neuartigen käfig-ion [(i-PrSn) 12 O 14 (OH) 6] …
H Puff, H Reuter
文献索引：Puff, H.; Reuter, H. Journal of Organometallic Chemistry, 1989 , vol. 373, p. 173 - 184
Abstract Single crystals of the compounds [(i-PrSn) 12 O 14 (OH) 6] Cl 2· L with L= 3H 2 O (I), 2DMF (II) and 4H 2 O· 4DMPU (III) have been isolated and investigated by an X-ray diffraction study. Common to all is the cage cation [(i-PrSn) 12 O 14 (OH) 6] 2+ with a “football” like tin-oxygen framework from which the organic moieties produced. Square- pyramidally coordinated tin atoms and six-membered tin-oxygen rings with half-chair ...
