The Journal of Organic Chemistry

A General and Efficient Synthesis of. alpha.-Azido Ketones

T Patonay, RV Hoffman

文献索引：Patonay, Tamos; Hoffman, Robert V. Journal of Organic Chemistry, 1994 , vol. 59, # 10 p. 2902 - 2905

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被引用次数: 33

摘要

Although a-azido ketones 1 have been known for a long time? few reports of their synthetic utility have appeared because few systematic studies have been performed. Scattered papers describing their chemistry reveal that they behave quite differently than the related a- azido esters and that they could have significant synthetic utility. Their pyrolysis leads to a- imino ketoness5 (presumably via nitrenes) or 2-acylimidazoles if@-carbon atoms are not ...