Tetrahedron letters

Single-step preparation of allylic sulfides having 1-phenyltetrazole-5-thio group from allylic alcohols using S, S′-BIS (1-phenyl-1H-tetrazol-5-YL) dithiocarbonate and …

K Takeda, K Tsuboyama, K Torii, M Murata, H Ogura

文献索引：Takeda, Kazuyoshi; Tsuboyama, Kanoko; Torii, Katsumi; Murata, Maki; Ogura, Haruo Tetrahedron Letters, 1988 , vol. 29, # 33 p. 4105 - 4108

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被引用次数: 26

摘要

Summary: The reaction of allylic alcohols and S, S'-bis (l-phenyl-lz-tetrazol-5-yl) dithiocarbonate (1) gave allylic sulfides having 1-phenyitetrazole-5-thio group in a single step. Furthermore, these allylic sulfides could be applied to carbon-carbon bond and carbon- sulfur bond formations by using Grignard reagents or carbanions in the presence of a catalytic amount of copper (I) bromide or palladium (O), respectively.