Palladium??Catalyzed Addition of Silyl??Substituted Chloroalkynes to Terminal Alkynes

…, M Iwasaki, A Kondoh, H Yorimitsu…

文献索引：Wada, Tatsuya; Iwasaki, Masayuki; Kondoh, Azusa; Yorimitsu, Hideki; Oshima, Koichiro Chemistry - A European Journal, 2010 , vol. 16, # 35 p. 10671 - 10674

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被引用次数: 10

摘要

The transition-metal-catalyzed addition of a carbon–halogen σ-bond to an alkyne is a very useful and attractive reaction in organic synthesis because both a carbon–carbon bond and a carbon–halogen bond are formed simultaneously and atom-economically. The transformation can provide structurally complex haloalkenes that can be further modified by carbon–carbon bond-forming reactions including cross-coupling reactions. In spite of their ...